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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Compounds of the Type Cu3MSxSe4-x(M = Nb, Ta). Determination of Crystal Structure of Cu3TaSSe3The preparation, X-ray data, vibrational, and electronic spectra of Cu3NbS3Se, Cu3NbS2Se2, Cu3NbSSe3, Cu3TaS3Se, Cu3TaS2Se2, and Cu3TaSSe3 are reported. The powder patterns of all compounds could be indexed on the basis of a simple cubic lattice. The compounds crystallize in pseudo-sulvanite type with the sulfur and selenium atoms in random distribution.
    Notes: Es wird über die Darstellung, röntgenographische Untersuchung sowie Elektronen- und Schwingungsspektren von Verbindungen des Typs Cu3MSxSe4-x(M = Nb, Ta) berichtet. Die Verbindungen Cu3NbS3Se, Cu3NbS2Se2, Cu3NbSSe3, Cu3TaS3Se, Cu3TaS2Se2 und Cu3TaSSe3 kristallisieren kubisch im Pseudo-Sulvanit-Typ mit statistischer Verteilung der S- und Se-Atome im Gitter. Von Cu3TaSSe3 wurde die vollständige Kristallstruktur bestimmt.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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