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  • 1
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Studies on Selenium Compounds. LXV. On Compounds of the Type (CH3O)3 SeX with X = F, Cl, Br, NO3, AlCl4Reaction of Se(OCH3)4 with SeX4(X = Cl, Br)(mole ratio 3:1) yields (CH3O)3SeX. The compounds (CH3O)3SeX (X = F, NO3) are formed by reaction of (CH3O)3SeCl with the silver salts AgF and AgNo3, respectively. (CH3O)3SeAlcl4 is prepared by reaction of (CH3O)3SeCl with AlCl3. Some properties of the synthezised compounds and the ir spectra are given. From their data deduction concerning the nature of the chemical bonds in the compounds (CH3O)3SeX are possible.
    Notes: Die Verbindungen (CH3O)3SeX mit X = Cl und br bilden sich durch Umsetzung von Se(OCH3)4 mit SeX4(Molverhältnis 3:1). Die verbindungen (CH3O)3SeF und (Ch3O)3SeNO3 entstehen bei der Reaction des Chlorids (CH3O)3SeCl mit AgF bzw. AgNO3. Das (Ch3O)3SeCl reagiert mit AlCl3 zu (CH3O)3SeAlCl4. Einige Eigenschaften der Verbindungen und die IR-Spektren werden mitgeteilt. Die IR-Spektren gestatten Aussagen zur Natur der Bindungsverhältnisse in den (CH3O)3 SeX-Verbindungen.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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