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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 395 (1973), S. 50-62 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The vapourization equilibrium of silver chlorideBy means of a mass spectrometer, equipped with a KNUDSEN effusion cell, the saturation pressures over liquid AgCl have been measured. The main species of the gas phase are AgCl and Ag3Cl3, but not Ag3Cl2, which was to be expected from the recent literature. Data see “Inhaltsübersicht”. Derived bond enthalpies are given. Finally, the results are critically compared with literature data.
    Notes: Mit einem mit KNUDSEN- Zelle ausgerüsteten Massenspektrometer wurden die Sättigungsdrucke über flüssigem AgCl gemessen. Wesentliche Bestandteile des Dampfes sind AgCl und Ag3Cl3, nicht aber das nach neueren Literaturangaben zu erwartende Ag3CI2.Gewonnene Daten:\documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{l} \Delta {\rm H}_{{\rm 800}}^{\rm 0} \,({\rm AgCl,fl} \to {\rm AgCl,g) = 46,5 kcal} \\ \Delta {\rm H}_{{\rm 800}}^{\rm 0} \,(3\,{\rm AgCl,fl} \to {\rm Ag}_{\rm 3} {\rm Cl}_{\rm 3} {\rm,g) = 40,7 kcal} \\ \Delta {\rm H}_{{\rm 298}}^{\rm 0} \,({\rm AgCl,g = 22,0\,\, kcal; }\,\,\Delta {\rm H}_{{\rm 298}}^{\rm 0} \,({\rm Ag}_{\rm 3} {\rm Cl}_{\rm 3} {\rm,g = - 35,0 kcal}{\rm .} \\ \end{array} $$\end{document}Davon abgeleitete Bindungsenthalpien werden angegeben. Abschließend werden die Ergebnisse kritisch mit, Literaturangaben verglichen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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