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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 354 (1967), S. 192-200 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The infrared spectra of [(CH3)2GeS]3, [(C4H9)2GeS]3, [(C6H5)2GeS]3, [(CH3)2SnS]3, [(C4H9)2SnS]3, [(C6H5)2SnS]3 and [(C6H5)2PbS]3 are reported and assigned. With these data, and the crystal structure of [(C6H5)2SnS]3, the bonding nature in these molecules are discussed. Strong (p → d)π-double bond character for the Ge-S, Sn-S and Pb-S linkages could not be observed.
    Notes: Die Infrarot-Spektren von [(CH3)2GeS]3, [(C4H9)2GeS]3, [(C6H5)2GeS]3, [(CH3)2SnS]3, [(C4H9)2SnS]3, [(C6H5)2SnS]3 und [(C6H5)2PbS]3 werden mitgeteilt und zugeordnet. An Hand der gewonnenen Daten und der Kristallstruktur des trimeren Diphenylzinnsulfids werden die Bindungsverhältnisse diskutiert. Starke (p → d)π - Doppelbindungsanteile zwischen Ge, Sn und Pb einerseits und Schwefel andererseits können nicht beobachtet werden.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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