ISSN:
0170-2041
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Reactions of Amino Acids and Peptides, IV. - Synthesis of Furan Derivatives from N-Methyl Amino AcidsIn the reaction of N-methyl homophenylalanine and N-methyl norleucine with hexafluoroacetic anhydride the expected 1,3-oxazolidin-5-one derivatives are formed only as by-products. As main products 3-[methyl(trifluoroacetyl)amino]-2,5-bis(trifluoromethyl)furan derivatives could be isolated, the structures of which were identified by spectroscopic methods.
Notes:
Bei der Reaktion von N-Methylhomophenylalanin und N-Methylnorleucin mit Hexafluoracetanhydrid entstehen die erwarteten 1,3-Oxazolidin-5-on-Derivate nur als Nebenprodukte. Als Hauptprodukte konnten 3-[Methyl(trifluoracetyl)amino]-2,5-bis(trifluormethyl)furan-Derivate isoliert werden, deren Konstitutionen mit spektroskopischen Methoden ermittelt wurden.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.198119810910
