ISSN:
0170-2041
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Contributions to the Knowledge of the Corrin Chromophore, VIII1). - Note on Novel Metal Complexes of Descobalto-5,6-dioxo-5,6-secocobyrinic Heptamethyl EsterDescobalto-10-bromo-5,6-dioxo-5,6-secocobyrinic heptamethyl ester (3a) reacts with rhodium bis(carbonylchloride) to give 4a. The complex 4b has been obtained from 3b in the same way. The compound 3b reacts with palladium acetylacetonate to yield the complex 5b.
Notes:
Descobalto-10-brom-5,6-dioxo-5,6-secocobyrinsäure-heptamethylester (3a) wurde mit Rhodium-bis(carbonylchlorid) in 4a übergeführt. In gleicher Weise gelang die Umsetzung von 3b zu 4b. Mit Palladium-acetylacetonat lieferte 3b den Komplex 5b.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.198019800523