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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 1983-1986 
    ISSN: 1434-193X
    Keywords: Radicals ; Dioxygen trapping ; Radical reactions ; Singlet-triplet splitting ; Thermochemistry ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---From the oxygen and temperature dependence of the trapping rate of 7,7-difluorobenzocyclopropene (1) in the range 180-240 °C, the energy profile of the equilibrium 1 →←2 has been obtained. From the heat of hydrogenation of 1, its heat of formation is derived (ΔHof = +3.8 kcal·mol-1), as a result of which the heat of formation of the singlet state of the diradical 2 is estimated as 25.7 kcal·mol-1. Whereas the trapping experiments demonstrate unambiguously a triplet ground state for 2, only a lower limit for the singlet-triplet splitting (〉 6 kcal·mol-1) can be given.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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