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Induced Fit Selection of a Barbiturate Receptor from a Dynamic Structural and Conformational/Configurational Library (1999)

Berl, Volker ; Huc, Ivan ; Lehn, Jean-Marie ; [et al.]

Weinheim : Wiley-Blackwell

Liebigs Annalen 1999 (1999), S. 3089-3094

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ISSN: 1434-193X

Keywords: Dynamic combinatorial chemistry ; Molecular recognition ; Hydrogen bonding ; Hydrazone isomerization ; Barbiturate receptor ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The selection of the receptor presenting the strongest affinity for a barbiturate substrate from a dynamic combinatorial library of constituents differing in structure and conformation/configuration is described. The gradual addition of the barbiturate to an equilibrating mixture of hydrazone isomers leads to the quantitative shift towards a single species, 3, which presents highest complementarity to the substrate and yields the supramolecular entity 3:4.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

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