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Phenylethynyl- and Phenylethenylmetacyclophanes with π,π Interactions (1999)

Cao, Derong ; Schollmeyer, Dieter ; Meier, Herbert

Weinheim : Wiley-Blackwell

Liebigs Annalen 1999 (1999), S. 791-795

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ISSN: 1434-193X

Keywords: Cyclophanes ; Sulfur heterocycles ; Cyclisations ; Cesium effect ; ππ* transitions ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: -Two series of [8]metacyclophanes with cis or trans configurated double bonds or triple bonds in the bridges were prepared; the first series 6, 8, and 10 contains phenylethynyl, the second series 13, 14, and 15 phenylethenyl substituents so that ππ interactions between the π centres in the bridge and the π centres of the basic chromophores tolan and trans-stilbene, respectively, can be studied.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

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