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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 771-774 
    ISSN: 1434-193X
    Keywords: Natural products ; Glycosphingolipids ; Gangliosides ; Starfish ; Linckialaevigata ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -A ganglioside molecular species [LLG-3 (1)] has been obtained from the water-soluble lipid fraction of the CHCl3/MeOH extract of the starfish Linckialaevigata. On the basis of chemical and spectroscopic findings, the structure of 1 has been elucidated. Negative-ion FABMS provided important information concerning both the structure of the sugar moiety and the molecular mass of the ganglioside. On the other hand, positive-ion FABMS/MS of [M + Na]+ ions obtained in the positive-ion FABMS of the ceramide lactoside (4) derived from 1 indicated the structure of the fatty acid chain of the ceramide moiety. 1 represents a new ganglioside molecular species possessing a 2→11-linked tandem-type disialosyl moiety.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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