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Synthesis of Acerogenin C and (+)-Acerogenin A, Two Macrocyclic Diarylheptanoid Constituents of Acer nikoense (1998)

Keserü, György Miklós ; Nógrádi, Mihály ; Szöllösy, Áron

Weinheim : Wiley-Blackwell

Liebigs Annalen 1998 (1998), S. 521-524

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ISSN: 1434-193X

Keywords: Acerogenin C ; (+)-Acerogenin A ; Synthesis ; Diarylheptanoids, macrocyclic ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The macrocyclic ketone acerogenin C (3) and the corresponding alcohol (+)-accerogenin A (1), diarylheptanoid constituents of the maple Acer nikoense were synthesized. The key steps were the selective reduction of the double bond of an α,β-unsaturated ketone (10) and macrocyclization of an iodophenol (13) by a modified Ullmann diarylether synthesis.

Type of Medium: Electronic Resource

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