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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 2000 (2000), S. 659-664 
    ISSN: 1434-1948
    Keywords: Perovskite phases ; Mixed conductors ; Materials science ; Neutron diffraction ; X-ray diffraction ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new series of perovskite-type materials of general formula La1.33NaxMnxTi2-xO6 (x = 0.66, 0.55 and 0.44) was obtained and characterized. The common structure is rhombohedral (space group R3cbar) although a transition to orthorhombic (space group Ibmm) is observed between 400 and 600  K for the  x   = 0.66 phase. Complex impedance techniques and charge/discharge cycles show a different electrical behavior that varies from a purely electronic conductor (x = 0.66) to a mixed electronic-ionic behavior for the other phases.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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