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Makrocyclisch modifizierte Verbindungen vom TTF- und TCNQ-Typ (1991)

Vögtle, Fritz ; Alfter, Frank ; Steckhan, Eberhard ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 897-902

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ISSN: 0009-2940

Keywords: Biphenylophane ; Kharasch coupling reaction ; Macrocycles ; TCNQ ; TTF ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Molecules of the TTF and TCNQ Type with Macrocyclic SkeletonsThe electron-rich and electron-poor macrocycles 1 - 3 have been synthesized. Their [1.1](3,3′)biphenylophane framework is formed by Kharasch reaction. Whereas in the well-known donors and acceptors I-III the functionalities are conjugated, in their macrocyclic “analogues” 1-3 the conjugation is prevented by the meta-connection of the phenylene rings. The redox properties - studied by cyclovoltammetry - are discussed. The X-ray analysis of 3 shows considerable deviations from a planar structure.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19911240433

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