Wiley InterScience Backfile Collection 1832-2000
Chemistry and Pharmacology
Reductive Arylation of Vinyl Trifluromethanesulfonates by Friedel-Crafts ReactionThe reaction of vinyl triflates 1 with benzene and toluene in the presence of aluminium trichloride gives alkyl-, alkenyl-, and 1,1-diarylalkanes 5, 6, 3, 9 depending on the structure of the substrate used. A mechanism for the reductive arylation is proposed.
Type of Medium: