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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemistry - A European Journal 1 (1995), S. 7-11 
    ISSN: 0947-6539
    Keywords: density-functional calculations ; ion-molecule reactions ; relativistic effects ; thermochemistry ; uranium compounds ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The nitridooxouranium cation NUO+ has been prepared as a new isoelectronic homologue to the uranyl dication UO22+ by a sequence of ionmolecule reactions starting from the atomic uranium cation U+. Collision-induced dissociation experiments and ligand-exchange reactions serve to unambiguously identify the ion as a species in which the uranium cation is formally inserted in the NO molecule. New thermochemical data for NUO+ and UN+ are given, and the stability of NUO+ with respect to UO22+ is investigated by means of quasi-relativistic density-functional calculations.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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