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Poulain, S. ; Noiret, N. ; Nugier-Chauvin, C. ; [et al.]

Weinheim : Wiley-Blackwell

Liebigs Annalen 1997 (1997), S. 35-40

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ISSN: 0947-3440

Keywords: Thiaoleic acids ; Chlorella ; Oleyl desaturase ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: New thiaoleic acid methyl esters 1 have been prepared as models for studies on Δ12-saturation, Convergent synthetic pathways to those acids from the 10-(tetrahydropyranyloxy)-dec-1-yne 2 are described. After saponification, their inhibitory effect on the in vivo desaturation of [1-14C] oleic acid into [1-14C] linoleic acid has been evaluated using green algae, Chlorella sorokiniana, as a biological model. This result may indicate that the oleyl-desaturase initiates dehydrogenation of a normal substrate by hydrogen atom abstraction at C-13.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.199719970108

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