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Crystallization kinetics of pure and binary melts (1969)

Kirwan, D. J. ; Pigford, R. L.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 15 (1969), S. 442-449

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ISSN: 0001-1541

Keywords: Chemistry ; Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: An absolute rate theory based on a plausible model of the activated state, was developed for the interfacial kinetics of crystal growth from the melt. Except for liquid metals the theory predicts the growth rates of pure materials within about an order of magnitude. A microinterferometric technique was employed to observe liquid compositions near the faces of crystals growing from binary melts. For the simple eutectic system composed of salol and thymol, the theory represents the composition and temperature dependence of the growth rate.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/aic.690150326

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