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Massenspektrometrische Untersuchungen zu Dyotropen Umlagerungen (1976)

Schwarz, Helmut ; Kliment, Miroslav ; Reetz, Manfred T. ; [et al.]

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 11 (1976), S. 989-994

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: The electron impact induced cleavage of the oxygen-carbon (or oxygen-silicon) bond is accompanied by an intramolecular migration of the silyl function onto the oxygen. Details of the mechanism formally correspond with a dyotropic rearrangement.

Notes: Die elektronenstoßinduzierte spaltung der Sauerstoff-Kohlenstoff-(bzw. silicium)-Bindung wird durch eine gleichzeitige Wanderung der Silylfunktion zum Sauerstoff ermöglicht. Der mechanistische Verlauf entspricht teilweise dem von dyotropen Umlagerungen.

Additional Material: 3 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210110911

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