ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The NMR chemical shift method was applied for the determination of the magnetic susceptibility of paramagnetic transition metal complexes in solution. The method was found to be very useful for the determination of magnetic susceptibility changes during a chemical reaction in which one paramagnetic compound produced another. The concentrations of two paramagnetic cobalt complexes [Co3O(O2CCH3)6(HO2CCH3)3] and Co(O2CCH3)2, were calculated from the chemical shift value observed during their reaction with cumene hydroperoxide. The results are consistent with those obtained from electronic spectra.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270190111