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Determination of the dissociation potentials of metal complexes by computerized flow-injection potentiometric stripping analysis (1990)

Fayyad, Manar

Weinheim : Wiley-Blackwell

Electroanalysis 2 (1990), S. 631-635

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ISSN: 1040-0397

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A method is described for determining the dissociation potentials of metal complexes using computerized flow-injection potentiometric stripping analysis (CFIPSA). The dissociation potentials of Bi:NTA and Bi:EDTA complexes are determined at pH 2 by measuring the bismuth(III) concentrations (i.e., the counts in solutions containing the 1:1 complexes at different deposition potentials between -0.15 and -0.90 V vs. Ag/AgCl). Dissociation potentials of -0.35 and -0.50 V vs. Ag/AgCl have been found for Bi:NTA and Bi:EDTA, respectively.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/elan.1140020810

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