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Dependence of selectivity and resolution upon composition of the binary mobile phase in LSC (1983)

Jaroniec, M. ; Suprynowicz-Sieńko, D.

Weinheim : Wiley-Blackwell

Journal of High Resolution Chromatography 6 (1983), S. 27-30

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ISSN: 0935-6304

Keywords: Liquid chromatography ; LSC with binary eluents ; Resolution in LSC ; Selectivity in LSC ; Adsorption LC ; Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The recently derived general equation for the capacity ratio has been utilized to study the dependence of selectivity and resolution upon mobile phase composition. This equation accounts for differences in molecular size of solutes and solvents, and for the energetic heterogeneity of the adscrbent surface. Model calculations illustrating the influence of these factors on the selectivity and resolution are presented and discussed.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jhrc.1240060106

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