ISSN:
1434-1948
Schlagwort(e):
Chromates
;
Catalytic transfer hydrogenation
;
Hydrogenations
;
Reductions
;
α,β-Unsaturated ketones
;
Asymmetric synthesis
;
Chemistry
;
General Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
In the presence of a HCO2H/Et3N (1:1) mixture, KHCr(CO)5 is an efficient catalyst precursor for the transfer hydro-genation of ketones in THF at room temperature. KHCr(CO)5 is also a stoichiometric reagent for the selective reduction of the carbon-carbon double bond of α,β-unsaturated ketones.
Zusätzliches Material:
1 Tab.
Materialart:
Digitale Medien