ISSN:
1434-193X
Schlagwort(e):
Asymmetric catalysis
;
Catalysis
;
Addition reactions
;
N ligands
;
Nickel
;
Chemistry
;
General Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
---Quaternary stereocenters were constructed with an enantioselectivity of up to 91% ee under aerobic conditions and at ambient temperature in the Michael reaction of β-dicarbonyl compounds and methyl vinyl ketone with Ni(OAc)2·4H2O and optically active trans-1,2-diaminocyclohexane as a chiral catalyst.
Zusätzliches Material:
1 Tab.
Materialart:
Digitale Medien