ISSN:
0951-4198
Schlagwort(e):
Chemistry
;
Analytical Chemistry and Spectroscopy
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Physik
Notizen:
Collisional Activation, charge-stripping and neutralization/reionozation mass spectra allow the identification of six [C6H7N]+· isomers, namely the molecular ions of the three isomeric picolines, 1+·-;3+·, ionized 2- and 4-methylene dihydropyridines, b - c, and ionized pyridinium methylide, a. The implication of the distonic forms a and b in some fragmentation reactions of funct of onalized (position 2) pyyridines is briefly discussed. Molecular orbital calculations indicate the b〉a〉1+· stability sequence.
Zusätzliches Material:
2 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/rcm.1290060212
