Publication Date:
2018-01-09
Description:
Ce-doped zirconia ceramics with general stoichiometry of Zr 1- x Ce x O 2 (0 ≤ x ≤ 1) have been obtained by substituting of Ce 4+ for Zr 4+ in ZrO 2 . The phase and microstructure evolutions of the ceramics were investigated and the effects of composition, temperature and pH value on the chemical durability of the ceramics were also studied. The results show that the phase transformation from monoclinic to tetragonal takes place at about x = 0.2 and from tetragonal to cubic at about x = 0.6. It is found that the increase of Ce content and/or sinter temperature promote the phase transformation. The leaching studies show that the normalized leaching rates of Ce (LR Ce ) increase with increasing Ce content. Moreover, LR Ce in acid solution are higher than those in neutral and alkaline solution. After 42 days, LR Ce is 10 -5 ~ 10 -7 g m −2 d −1 under all different leaching conditions, exhibiting their excellent chemical durability. This article is protected by copyright. All rights reserved.
Print ISSN:
1546-542X
Electronic ISSN:
1744-7402
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
