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Crystal structure of 2-aminopyridinium 6-chloronicotinate (2015)

Jasmine, N.J.Rajam, A.Muthiah, P.T.Stanley, N.Razak, I.A.Rosli, M.M.

International Union of Crystallography (IUC)

In: Acta Crystallographica Section E

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Publication Date: 2015-08-13

Description: In the title salt, C5H7N+·C6H3ClNO−, the 2-aminopyridinium cation interacts with the carboxylate group of the 6-chloronicotinate anion through a pair of independent N—H...O hydrogen bonds, forming an R22(8) ring motif. In the crystal, these dimeric units are connected further via N—H...O hydrogen bonds, forming chains along [001]. In addition, weak C—H...N and C—H...O hydrogen bonds, together with weak π–π interactions, with centroid–centroid distances of 3.6560 (5) and 3.6295 (5) Å, connect the chains, forming a two-dimensional network parallel to (100).

Keywords: crystal structure2-aminopyridinium6-chloronicotinate6-chloropyridine-3-carboxylatenoncovalent interactionsπ–π stacking interactions

Electronic ISSN: 1600-5368

Topics: Chemistry and Pharmacology , Geosciences

Published by International Union of Crystallography (IUC)

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