ALBERT

Description: We conduct first principles calculations to determine the relative stability field and elasticity contrast of serpentine polymorphs at pressure and temperature conditions relevant to the oceanic lithosphere and subduction zone. At high pressures(〉4 GPa), the corrugated form of serpentine polymorph(antigorite, Atg) plus brucite(Brc) assemblage is thermodynamically more favorable compared to its planar counterpart(lizardite, Liz). The phase boundary between Liz and Atg+Brc exhibits a negative slope in the whole P-T range, indicating this transition can be driven by increasing either pressure or temperature. Near 0 GPa, the slope is about −33 K/GPa. As pressure exceeds 1 GPa, the transition temperature starts to decrease more rapidly. Because of the corrugated nature of its constituent layers, Atg is more susceptible to intra-layer deformations( 7 to 36% smaller C 11 , C 22 , C 12 and C 66 at ambient conditions) while more resistant to interlayer shear deformation ( 25 % larger C 44 , 36 % larger C 55 ) than Liz. In contrast, their responses to the interlayer compressive deformation( C 33 ) are similar. For isotropic polycrystalline aggregates at pressures between 0 to 4 GPa, Atg exhibits a smaller bulk modulus( 12 to 15 %) and a larger shear modulus( 6 to 11 %) than Liz, while their density contrast is within 1%. Accordingly, a Liz/Atg transition is accompanied by a decrease in V p (2 to 3 %), an increase in V s (3 to 5 %), and a more pronounced drop in V p /V s (6 to 8 %). These results may help to identify and characterize serpentine polymorphs produced under various geological settings.