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Throughâspace interactions in enshrouded mâterphenylsilanes (2014)

Paola Romanato, Simon Duttwyler, Anthony Linden, Kim K. Baldridge, Jay S. Siegel

Wiley

In: Journal of Physical Organic Chemistry

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Publication Date: 2014-01-18

Description: A series of m âterphenylâsubstituted silanes was prepared and studied with regard to the steric and electronic interactions between the silyl core and the terphenyl shroud. Only weak conformational preferences were observed for the core, but the Ïâbasicity of the lateral rings led to distinct nuclear magnetic resonance shifts, and o âfluorine atoms led to throughâspace coupling effects. Copyright Â© 2014 John Wiley & Sons, Ltd. The steric and electronic interactions between the silyl core and the terphenyl shroud of a series of m âterphenylâsubstituted silanes were investigated by Xâray crystallography, nuclear magnetic resonance spectroscopy, and computation.

Print ISSN: 0894-3230

Electronic ISSN: 1099-1395

Topics: Chemistry and Pharmacology , Physics

Published by Wiley

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