Publication Date:
2013-09-22
Description:
In the title complex, [HgI2(C21H19N5)2], the HgII ion is located on a twofold rotation axis and is coordinated by two I atoms and two N atoms from two (E)-2-(3-(4-(1H-1,2,4-triazol-1-yl)styryl)-5,5-dimethylcyclohex-2-enylidene)malononitrile ligands in a distorted tetrahedral geometry. In the crystal, the molecules are linked by intermolecular π–π interactions between the triazole and benzene rings [centroid–centroid distance = 3.794 (3) Å] into a band extending in [010]. These bands are further connected by C—H...N hydrogen bonds into a two-dimensional network parallel to (100).
Electronic ISSN:
1600-5368
Topics:
Chemistry and Pharmacology
,
Geosciences