Publication Date:
2013-08-24
Description:
Abstract. Two new coordination polymers {[Cd 2 (BDC) 2 (3-bpmp)(H 2 O) 2 ] · 2H 2 O} n ( 1 ) and [Cd 2 (BDC) 2 (4-bpmp)] n ( 2 ) [H 2 BDC = 5-hydroxy-isophthalic acid, 3-bpmp = 1,4-bis(3-pyridylmethy)piperazine, and 4-bpmp = 1,4-bis(4-pyridylmethy) piperazine] were synthesized via hydrothermal synthesis, and further characterized by IR spectroscopy, elemental analysis, XRD, and X-ray crystallography. Complex 1 shows a two-dimensional (4,4) sql topology and complex 2 features an 8-connected hex topology. Moreover, the luminescent properties of complexes 1 and 2 were investigated in the solid state at room temperature.
Print ISSN:
0044-2313
Electronic ISSN:
1521-3749
Topics:
Chemistry and Pharmacology