ALBERT

Description:    Unbleached (UN), oxygen-delignified and fully-bleached (FB) birch fibers with a residual lignin content of ca. 3, 2 and 〈1 %, respectively, were used to produce nanofibrillated cellulose (NFC) and nanopaper by using an overpressure device. The tensile index, elongation and elastic modulus of nanopaper were compared and the effect of residual cell wall components accessed. Under similar manufacturing conditions, UN NFC produced nanopaper with a density of 0.99 g/cm 3 , higher than that from FB NFC (0.7 g/cm 3 ). This translated in much lower air permeability in the case of UN nanopaper (1 and 11 mL/min for UN and FB samples, respectively). Fundamentally, these observations are ascribed to the finer fibrils produced during microfluidization of UN fibers compared to those from lower yield counterparts (AFM roughness of 8 and 17 nm and surface areas of 124 and 98 m 2 /g for NFC from UN and FB fibers, respectively). As a result, values of stress at break and energy absorption of nanopaper from high yield fibers are distinctively higher than those from fully bleached NFC. Interactions of water with the surface and bulk material were affected by the chemical composition and structure of the nanofibrils. While UN nanopaper presented higher water contact angles their sorption capacity (and rate of water absorption) was much higher than those measured for nanopaper from FB NFC. These and other observations provided in this contribution are proposed to be related to the mechanoradical scavenging capacity of lignin in high shear microfluidization and the presence of residual heteropolysaccharides. Content Type Journal Article Category Original Paper Pages 1-15 DOI 10.1007/s10570-012-9788-z Authors Ana Ferrer, Department of Chemical Engineering, University of Cordoba, Cordoba, Spain Elisabet Quintana, Textile and Paper Engineering Department, Universitat Politècnica de Catalunya, 08222 Terrassa, Spain Ilari Filpponen, School of Chemical Technology, Department of Forest Products Technology, Aalto University, 00076 Aalto, Finland Iina Solala, School of Chemical Technology, Department of Forest Products Technology, Aalto University, 00076 Aalto, Finland Teresa Vidal, Textile and Paper Engineering Department, Universitat Politècnica de Catalunya, 08222 Terrassa, Spain Alejandro Rodríguez, Department of Chemical Engineering, University of Cordoba, Cordoba, Spain Janne Laine, School of Chemical Technology, Department of Forest Products Technology, Aalto University, 00076 Aalto, Finland Orlando J. Rojas, School of Chemical Technology, Department of Forest Products Technology, Aalto University, 00076 Aalto, Finland Journal Cellulose Online ISSN 1572-882X Print ISSN 0969-0239