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α-Cs2Cr3O10 (2012)

Kolitsch, U.

International Union of Crystallography (IUC)

In: Acta Crystallographica Section E

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Publication Date: 2012-06-13

Description: The title compound, dicaesium trichromium(VI) oxide, is the orthorhombic (space group Pbca) modification of Cs2Cr3O10. The compound is isotypic with its NH4 and Rb trichromate analogues. The structure contains discrete [Cr3O10]2− anions [Cr—O—Cr = 136.58 (11) and 140.30 (12)°] linked via two non-equivalent irregularly 11-coordinated Cs+ cations [dav(Cs—O) = 3.224 and 3.272 Å]. All atoms are in general positions.

Electronic ISSN: 1600-5368

Topics: Chemistry and Pharmacology , Geosciences

Published by International Union of Crystallography (IUC)

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