Publication Date:
2019
Description:
〈p〉Publication date: 15 October 2019〈/p〉
〈p〉〈b〉Source:〈/b〉 Acta Materialia, Volume 179〈/p〉
〈p〉Author(s): T. Glechner, R. Hahn, T. Wojcik, D. Holec, S. Kolozsvári, H. Zaid, S. Kodambaka, P.H. Mayrhofer, H. Riedl〈/p〉
〈div xml:lang="en"〉
〈h5〉Abstract〈/h5〉
〈div〉〈p〉Using a combination of density functional theory calculations and nanomechanical testing of sputter-deposited, 110-oriented Ta〈sub〉0.47〈/sub〉C〈sub〉0.34〈/sub〉N〈sub〉0.19〈/sub〉 thin films, we show that non-metal alloying – substituting C with N atoms – in TaC results in a super-hard material with enhanced ductility. Based on the calculated elastic constants, with Pugh and Pettifor criteria for ductile character, we predict that stoichiometric and sub-stoichiometric Ta-C-N alloys are more ductile than Ta-C compounds. From nanoindentation of the as-deposited coating, we measure hardness of 43 ± 1.4 GPa. 〈em〉In situ〈/em〉 scanning electron microscopy (SEM) based micro-compression of cylindrical pillars, prepared via focused ion beam milling of the coating, revealed that Ta-C-N alloys are ductile and undergo plastic deformation with a yield strength of 17 ± 1.4 GPa. The post-compression SEM images of the pillars show {111} 〈〈math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si1.svg"〉〈mrow〉〈mn〉01〈/mn〉〈mrow〉〈mover accent="true"〉〈mn〉1〈/mn〉〈mo〉¯〈/mo〉〈/mover〉〈/mrow〉〈/mrow〉〈/math〉〉 as the active slip system operating during compression. Additional 〈em〉in situ〈/em〉 SEM based cantilever tests suggest that the Ta-C-N films exhibit superior fracture toughness compared to Ta-C coatings. Our results provide a new perspective on the role of alloying on the mechanical behavior of ultra-high temperature compounds such as transition-metal carbides.〈/p〉〈/div〉
〈/div〉
〈h5〉Graphical abstract〈/h5〉
〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S1359645419305257-fx1.jpg" width="490" alt="Image 1" title="Image 1"〉〈/figure〉〈/p〉〈/div〉
Print ISSN:
1359-6454
Electronic ISSN:
1873-2453
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics