Publication Date:
2018
Description:
〈b〉Chemical ionisation quadrupole mass spectrometer with an electrical discharge ion source for atmospheric trace gas measurement〈/b〉〈br〉
Philipp G. Eger, Frank Helleis, Gerhard Schuster, Gavin J. Phillips, Jos Lelieveld, and John N. Crowley〈br〉
Atmos. Meas. Tech. Discuss., https//doi.org/10.5194/amt-2018-428,2018〈br〉
〈b〉Manuscript under review for AMT〈/b〉 (discussion: open, 0 comments)〈br〉
We present a Chemical Ionisation Quadrupole Mass Spectrometer (CI-QMS) with a novel discharge ion source. In addition to the expected detection of PAN, peracetic acid and ClNO〈sub〉2〈/sub〉, the instrument is also sensitive to SO〈sub〉2〈/sub〉, HCl and acetic acid through ion chemistry unique for our ion source. We present ionisation schemes along with illustrative data sets from field campaigns underlining the potential of the CI-QMS as an alternative to polonium, especially for application in the marine boundary layer.
Print ISSN:
1867-1381
Electronic ISSN:
1867-8548
Topics:
Geosciences