Electronic Resource
Oxford, UK
:
Blackwell Publishing Ltd
Journal of metamorphic geology
13 (1995), S. 0
ISSN:
1525-1314
Source:
Blackwell Publishing Journal Backfiles 1879-2005
Topics:
Geosciences
Notes:
Abstract Quartz-hosted, synthetic CO2-H2O fluid inclusions behave as open systems with respect to diffusional transfer of hydrogen during laboratory-simulated metamorphic re-equilibration at 650, 750 and 825°C and 1.5 kbar total pressure with fO2 defined by the C-CH4 buffer. Microthermometry and Raman spectroscopy show that the initial CO2-H2O inclusions become CO2-CH4-H2-H2Oinclusions after diffusive influx of hydrogen from the reducing confining medium. Measurable changes are observed in inclusion compositions after only 15 days of re-equilibration, implying significant hydrogen mobility at still lower temperatures over geological time spans. Results of synthetic inclusion re-equilibrium experiments have profound implications for the interpretation of natural fluid-inclusion data; failure to account for potential hydrogen migration in inclusions from high-temperature geological environments may lead to erroneous estimates of P-T, and/or the compositions of metamorphic fluids.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1111/j.1525-1314.1995.tb00224.x
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