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Hydrogen-bond structure in an aqueous solution of sodium chloride at sub- and supercritical conditions (1997)

de Jong, P. H. K. ; Neilson, G. W.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 107 (1997), S. 8577-8585

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The method of neutron diffraction and isotopic substitution was used to determine the hydrogen-bond structure as defined by gOH(r) in a 1 m aqueous electrolyte solution of sodium chloride at two thermodynamic states, one subcritical with T=300 °C and P=120 bar, and the other supercritical T=460 °C and P=800 bar (the critical temperature of 1 m sodium chloride is 425 °C). The results are similar to those found in pure water substance, and confirm the progressive disruption of the hydrogen bond network brought about by an increase in temperature. © 1997 American Institute of Physics.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.475010

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