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Influence of the environment on the excited state deactivation in functionalized quinque-thienyls (2001)

Lanzani, G. ; Cerullo, G. ; De Silvestri, S.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 115 (2001), S. 1623-1625

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The transient photoinduced transmission of quinquethiophene-S,S-dioxide in solution is reported. Stimulated emission is observed in the viscous solvent, but quenched in polar and nonpolar low viscosity solvents. The lifetime of the photoexcited state changes of more than one order of magnitude depending on the solvent properties, pointing out conformational effects. Low-energy coherent transient is observed and assigned to real time conformational dynamics. © 2001 American Institute of Physics.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.1386936

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