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Identification of the ν1(σ) mode of linear GeC3Si (2002)

Robbins, D. L. ; Rittby, C. M. L. ; Graham, W. R. M.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 117 (2002), S. 3811-3815

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The first optical observation of a mixed germanium-silicon-carbon (GelSimCn) cluster has been made by trapping the products of the laser ablation of carbon/silicon/germanium rods in Ar at 10 K. The ν1(σ) C–C stretching mode of linear GeC3Si has been identified at 1939.0 cm−1. The assignment is confirmed by the very good agreement between Fourier transform infrared (FTIR) measurements of frequencies and isotopic shifts and predictions of our quantum theoretical calculations. © 2002 American Institute of Physics.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.1495406

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