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Fine structure effect on the charge transfer reaction of Ar+(2P3/2,1/2)+N2 (X˜ 1Σ+g, v=0) (1986)

Liao, C. L. ; Xu, R. ; Ng, C. Y.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 84 (1986), S. 1948-1950

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The relative spin-orbit-state-selected total charge transfer cross sections, σ3/2 and σ1/2, for the reactions, Ar+ (2P3/2,1/2)+N2 (X˜ 1∑+g ,v=0) → Ar+N+2 at the center-of-mass collision energy (Ec.m.) range of 0.41–164.7 eV, have been determined using the photoionization and crossed ion–neutral beam methods. The kinetic energy dependences for σ1/2/σ3/2 is found to exhibit a minimum at Ec.m.≈3.3 eV, an observation consistent with the prediction of a recent semiclassical theoretical calculation of Spalburg and Gislason.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.450399

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