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A photoionization study of SeH and H2Se (1986)

Gibson, S. T. ; Greene, J. P. ; Berkowitz, J.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 85 (1986), S. 4815-4824

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The photoion yield curve of SeH, prepared by the reaction H+H2Se is presented. The adiabatic I.P. is 9.845±0.003 eV, and autoionization structure is observed, from which higher I.P.'s are inferred. The photoion yield curves of H2Se+, SeH+, and Se+ from H2Se are also measured. The fragmentation thresholds, together with I.P. (SeH), enable one to infer the bond energies D0(HSe−H)=78.99±0.18 kcal/mol and D0(SeH)=74.27±0.23 kcal/mol. The adiabatic I.P. for H2Se (X˜ 2B) is 9.886±0.003 eV.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.451715

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