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Detection of HBNH by infrared diode laser spectroscopy (1987)

Kawashima, Yoshiyuki ; Kawaguchi, Kentarou ; Hirota, Eizi

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 87 (1987), S. 6331-6333

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The infrared spectrum of a transient species HBNH was observed in the gas phase using a diode laser spectrometer. The HBNH molecule is formed in an ac discharge plasma of a diborane/ammonia or diborane/nitric oxide mixture. The ν3 band origin and the rotational constants of H11BNH were determined to be ν0=1786.193 08(72), B0=1.099 335(81), and B3=1.093 481(72) cm−1, with three standard deviations in parentheses. The ν3 band of H10BNH was also observed and analyzed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.453462

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