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Translational component of the interaction-induced dipole correlation functions in dense fluids (1987)

Gburski, Z. ; Samios, J. ; Dorfmüller, T.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 87 (1987), S. 7348-7349

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The correlation functions associated with the translational motion of a dipole induced by the permanent multipoles of an order l=1,2,3,... in dense media have been calculated analytically assuming the isotropic diffusion mechanism. The reflecting wall boundary condition at the distance of the closest approach of two molecules has been taken into account. The translational correlation functions obtained from this model have been compared with the results of molecular dynamics simulations in liquids N2 and CS2, and good agreement has been obtained.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.453332

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