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Spectroscopic study of the E 1Σ+g "shelf'' state in 7Li2 (1987)

Bernheim, R. A. ; Gold, L. P. ; Tomczyk, C. A. ; [et al.]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 87 (1987), S. 861-868

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The E 1Σ+g "shelf '' state of the 7Li2 molecule was investigated using a pulsed optical optical double resonance technique. The measurements cover the vibrational levels in the range 0≤v≤29 including the shelf region around 13≤v≤15. Molecular constants have been determined. Using an inverted perturbation approach, an effective potential energy curve has been generated within the adiabatic approximation whose quantum mechanical energy eigenvalues reproduce all the measured term values to within 0.113 cm−1 for the range 0≤v≤23 and 0≤J≤47.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.453293

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