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High resolution spectroscopy of diphenyldecapentaene and diphenyldodecahexaene (1987)

Horwitz, James S. ; Itoh, Takao ; Kohler, Bryan E. ; [et al.]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 87 (1987), S. 2433-2437

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Fluorescence and fluorescence excitation spectra of single crystal and polycrystalline solutions of diphenyldecapentaene in n-decane and diphenyldodecahexaene in n-dodecane have been measured at 77 and 4.2 K. At 4.2 K the spectra are well resolved (FWHM bandwidths (approximately-equal-to)10 cm−1) and, for the principal site, the energy for the 2 1Ag(S1) to 1 1Ag(S0) origin band of diphenyldecapentaene in n-decane is 20 133.3 cm−1 and that of diphenyldodecahexaene in n-dodecane is 18 261.4 cm−1. Analysis of these data includes the determination of fluorescence decay rates and C–C and C=C vibrational frequencies in the ground and excited states.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.453134

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