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Equation of state of 1-butene shocked to 54 GPa (540 kbar) (1988)

Hamilton, D. C. ; Mitchell, A. C. ; Ree, F. H. ; [et al.]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 88 (1988), S. 7706-7708

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Hugoniot equation-of-state data for liquid 1-butene were measured in the shock pressure range 12–54 GPa (120–540 kbar) using a two-stage light-gas gun. The data are compared with previous data for polybutene, a stoichiometrically equivalent liquid with a smaller initial specific volume. The data for both butenes are in agreement with chemical equilibrium calculations which assume that shock-compressed hydrocarbons dissociate and form a two-phase mixture consisting of molecular hydrogen and carbon in a stiff, diamond-like phase.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.454284

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