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Matrix infrared study of NH−2 produced by electron impact on NH3 (1988)

Suzer, Sefik ; Andrews, Lester

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 89 (1988), S. 5347-5349

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Electron impact of dilute Ar/NH3 samples during condensation at 12 K produced six new infrared bands: 3552, 3217, 3152, 3133, 1523, and 1496 cm−1. The 3552 cm−1 band has been assigned to OH−, the 3133 cm−1 band to NH, and the 3217 and 1496 cm−1 bands to NH2 radical by earlier workers. The 3152 and 1523 cm−1 bands exhibit proper 15N shifts to be assigned to the NH−2 anion isolated in solid argon.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.455604

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