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  • 1
    Electronic Resource
    Electronic Resource
    An explanation of the 1D2 anomalous crystal field splitting in PrCl3 (1989)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 5280-5283 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Taking into account configuration interaction between 4f2 and 4f15d1 via the odd rank crystal field parameters eliminates most of the well-known discrepancy of the 1D2 multiplet of trivalent praseodymium in PrCl3, found when "standard'' crystal field treatment is applied to experimental data. Ab initio values of crystal field parameters agree with the new parameters including the configuration interaction.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.456431
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