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Ionization potentials of large van der Waals molecules (1989)

Horin, Narda Ben ; Even, Uzi ; Jortner, Joshua

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 91 (1989), S. 331-339

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: In this paper we provide an extension of the electrostatic model for the structure and energetics of large van der Waals ions consisting of an aromatic cation bound to rare-gas atoms. We consider the effects of intermolecular electronic overlap on the charge-induced dipole interactions. Model calculations for tetracene⋅R+n (n=1–3 and R=Ar, Kr) and for benzene⋅R+ provide a reasonable account for the ionization potentials of these vdW ions.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.457465

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