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Stochastic dynamics of the chlorite–iodide reaction (1990)

Sagués, F. ; Ramírez-Piscina, L. ; Sancho, J. M.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 92 (1990), S. 4786-4792

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: A recently proposed theoretical framework appropriate to the study of the stochastic behavior of several chemical systems is used to analyze the irreproducibility of the observed reaction times in the chlorite–iodide clock reaction. Noise terms are incorporated through the kinetic constants and their intensity is further correlated with the inverse of the stirring rate. Analytical and simulation results are obtained for the first moments of the reaction time distribution. These results are compared with recent experimental data obtained by Nagypál and Epstein.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.457696

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