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Excited-state dipole moments of SO2. II (1992)

Heitz, S. ; Schmalzigaug, K. ; von Moers, F. ; [et al.]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 97 (1992), S. 7174-7179

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Determination of electric dipole moments on SO2 molecules in the region of the A˜ 1A2 and B˜ 1B1 states is reported. The Stark splittings and shifts of single rovibronic lines in several vibronic bands were measured by high-resolution laser spectroscopy in a supersonic molecular beam. Electric-field strengths of up to 12 kV/cm were applied. The dipole moment of the A˜ 1A2 state was determined to be 1.79(5) D, whereas an indication of a clearly smaller dipole moment was found for the B˜ 1B1 state.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.463542

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